Video calls need permission at two levels: your operating system has to allow the browser to use the camera and microphone, and the browser has to allow this site to use them. Both have to be on for video to work.
If you only do one thing:
Open your video session, click Join Video Call, and accept the browser's “Allow camera and microphone?” prompt. If you don't see a prompt, the steps below are probably what you need.
When you click Join Video Call, the browser shows a prompt asking to use your camera and microphone — click Allow. If you accidentally blocked it earlier:
teachersdelivered.co.uk to Allow. Then close and reopen the tab.Sharing a PowerPoint and want to move through the slides while still seeing your pupil? Use the call's pop-out button: it floats your pupil's video in a small window that stays on top of everything — including a full-screen slideshow.

No pop-out button? (older browsers, or the classic layout)
Run the slides in a window rather than full screen — full screen would hide the call:
Two screens? Even easier — run the slideshow full screen on one monitor, keep the call on the other, and share that monitor.